Aktuelles

Die Fachgruppe Festkörperchemie & Materialforschung verlieh anlässlich der 21. Vortragstagung für Anorganische Chemie am 27.09.2022 in Marburg die Rudolf-Hoppe-Vorlesung an Professor Thomas Fässler (Technische Universität München) in Würdigung seiner herausragenden Arbeiten zu Lithiumionen-Leitern. …

Dr. Terrance Hadlington, Nachwuchsgruppe am Lehrstuhl für Anorganische Chemie mit Schwerpunkt Neue Materialien (Prof. Fässler), wird mit dem Wöhler-BASF-Nachwuchspreis ausgezeichnet, den die Wöhler-Vereinigung für Anorganische Chemie der Gesellschaft Deutscher Chemiker (GDCh) vergibt. Die…

A team of German and Dutch scientists synthesized a series of substances, which show bright luminescence under UV light.  “The compounds decompose upon contact with oxygen or moisture. Because of that, all chemicals must be thoroughly dried in specialized vacuum ovens and all manipulations must be…

Li9GaP4, reveals a high superionic conductivity of 1.6 mS cm–1 and a low activation energy. Li9GaP4 is easily accessible via ball milling of the elements and subsequent annealing at quite moderate temperatures. Temperature-dependent single-crystal X-ray diffraction reveals that lithium is not…

In this review, examples of borderline cases at the transition from “locally delocalized electrons” to delocalized electronic systems are summarized, with a special focus on examples that occur as anions in solution and in extended solids.    Klein W., Schier A., Fässler T.F. (2021) Molecules Meet…

The unique three‐dimensional structure of spherical, homoatomic nine‐atom germanium clusters opens various possibilities for the spatial arrangement of functional groups. Ligands comprising lone pairs have recently been introduced in the cluster sphere, and we now report the addition of a boranyl…

The lithium phosphidoaluminate Li9AlP4 represents a promising new compound with a high lithium ion mobility.This triggered the search for new members in the family of lithium phosphidotrielates, and the novel compounds Li3AlP2 and Li3GaP2, obtained directly from the elements via ball milling and…

Intermediates and products of the reaction of Zn(II) organyls with tetrel element Zintl ions: cluster extension versus complexation

Polyanionic Frameworks in the Lithium Phosphidogermanates Li2GeP2 and LiGe3P3 – Synthesis, Structure, and Lithium Ion Mobility

Fast Lithium Ion Conduction in Lithium Phosphidoaluminates T. M. F. Restle, Ch. Sedlmeier, H. Kirchhain, W. Klein, G. Raudaschl-Sieber, V. L. Deringer, L. van Wüllen, H. A. Gasteiger, T. F. Fässler Angew. Chem. Int. Ed. 2020 https://doi.org/10.1002/ange.201914613 Fast lithium ion conduction at…