Dr. Arseni Kostenko

Changing the Reactivity of Zero‐and Mono‐Valent Germanium with a Redox Non‐Innocent Bis (silylenyl) carborane Ligand

Shenglai Yao, Arseni Kostenko, Yun Xiong, Christian Lorent, Ales Ruzicka, Matthias Driess

Angew. Chem. Int. Ed. 2021, 60, 14864.

Synthesis and coordination ability of a donor-stabilised bisphosphinidene

Terrance J. Hadlington,* Arseni Kostenko, Matthias Driess,*

Chem. Eur. J. 2021, 27, 2476.

Isolable Dibenzo[a,e]disilapentalene with a Dichotomic Reactivity toward CO₂

Bochao Su, Arseni Kostenko, Shenglai Yao, and Matthias Driess*

J. Am. Chem. Soc. 2020 142, 40, 16935.­

Redox Non-Innocent Monoatomic Silicon(0) Complex (‘Silylone’): Its One-Electron-Reduction Induces an Intramolecular One-Electron-Oxidation of Silicon(0) to Silicon(I)

Shenglai Yao, Arseni Kostenko, Yun Xiong, Ales Ruzicka, Matthias Driess*

J. Am. Chem. Soc. 2020 142, 29, 12608.

A Systems Approach to a One-Pot Electrochemical Wittig Olefination Avoiding the Use of Chemical Reductant or Sacrificial Electrode

Biswarup Chakraborty, Arseni Kostenko, Prashanth W. Menezes, Matthias Driess*

Chem. Eur. J. 2020, 26, 11829.

Cycladdition Chemistry of a Silylene-Nickel Complex Toward Organic π-Systems: From Reversibility to C-H Activation

Terrance J. Hadlington,* Arseni Kostenko, Matthias Driess*

Chem. Eur. J. 2020, 26, 1958.

Mechanism of the Thermal Z⇌E Isomerization of a Stable Silene. Experiment and Theory

Lieby Zborovsky, Arseni Kostenko, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig*

Angew. Chem. Int. Ed. 2019, 58, 14524.

Silicon-Mediated Coupling of Carbon Monoxide, Ammonia, and Primary Amines to Form Acetamides

Marcel-Philip Luecke, Arseni Kostenko Yuwen Wang, Shenglai Yao, Matthias Driess*

Angew. Chem. Int .Ed. 2019, 58, 12940.

Silicon-Mediated Selective Homo- and Hetero-Coupling of Carbon Monoxide

Yuwen Wang,⁺ Arseni Kostenko,⁺ Terrance J. Hadlington,⁺ Marcel-Philip Luecke, Shenglai Yao, Matthias Driess

J. Am. Chem. Soc. 2019, 141 (1), 626.

The Role of the Fluoro‐ Hydrido‐ Phosphorane Intermediate in Catalytic Hydrosilylation of Acetophenone: Computational Study

Arseni Kostenko,* Roman Dobrovetsky*

Eur. J. Org. Chem. 2019, 318.

A Geometrically Compelled Disilene with λ⁴-Coordinate Si^II Atoms

Arseni Kostenko,* Matthias Driess*

J. Am. Chem. Soc. 2018, 140, 49, 16962.

Chelate Silylene–Silyl Ligand Can Boost Rhodium-Catalyzed C-H Bond Functionalization Reactions

Zhenbo Mo,⁺ Arseni Kostenko,⁺ Yu-Peng Zhou, Shenglai Yao, Matthias Driess*

Chem. Eur. J. 2018, 24, 14608.

Generation and Characterization of the First Persistent Platinum(I)-Centered Radical

Yosi Kratish, Arseni Kostenko, Alexander Kaushansky, Boris Tumanskii, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig,*

Angew. Chem. Int. Ed. 2018, 57, 8275.

An isolable β-diketiminato chlorosilylene

Yun Xiong, Shenglai Yao, Arseni Kostenko, Matthias Driess*

Dalton Trans. 2018, 47 (7), 2152.

Bis(silylenyl)-substituted ferrocene-stabilized 6-arene iron(0) complexes: synthesis, structure and catalytic application

Marcel-Philip Luecke, Digvijay Porwal, Arseni Kostenko, Yupeng Zhou, Shenglai Yao, Matthias Keck, Christian Limberg, Martin Oestreich, Matthias Driess *

Dalton Trans. 2017, 46 (47), 16412.

Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins

Yuwen Wang, Arseni Kostenko, Shenglai Yao, Matthias Driess*

J. Am. Chem. Soc. 2017, 139 (38), 13499.

Spectroscopic Observation of the Triplet Diradical State of a Cyclobutadiene

Arseni Kostenko, Boris Tumanskii, Yuzuru Kobayashi, Masaaki Nakamoto, Akira Sekiguchi,* Yitzhak Apeloig,*

Angew. Chem. Int. Ed. 2017, 56 (34), 10183.

Facile Access to NaOCAs and Its Use as an Arsenic Source to Form Germylidenylarsinidene Complexes.

Shenglai Yao, Yves Grossheim, Arseni Kostenko, Ernesto Ballestero-Martinez, Stefan Schutte, Mark Bispinghoff, Hansjoerg Gruetzmacher,* Matthias Driess*

Angew. Chem. Int. Ed. 2017, 56 (26), 7465.

Intriguing Physical and Chemical Properties of Phosphorus Corroles

Jenya Vestfrid, Rashmi Kothari, Arseni Kostenko, Israel Goldberg, Boris Tumanskii, Zeev Gross*

Inorg. Chem. 2016, 55, 6061.

Heavier congeners of CO and CO₂ as ligands: from zero-valent germanium ('germylone') to isolable monomeric GeX and GeX₂ complexes (X = S, Se, Te)

Yun Xiong, Shenglai Yao, Miriam Karni, Arseni Kostenko, Alexander Burchert, Yitzhak Apeloig,* Matthias Driess*

Chem. Sci. 2016, 7, 5462.

Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold Complexes

Liqun Jin, Mohand Melaimi, Arseni Kostenko, Miriam Karni, Yitzhak Apeloig,*  Curtis E. Moore,*  Arnold. L. Rheingold,* Guy Bertrand*

Chem. Sci. 2016, 7, 150.

Observation of a Thermally Accessible Triplet State Resulting from Rotation around a Main Group π-bond

Arseni Kostenko, Boris Tumanskii, Miriam Karni, Shigeyoshi Inoue, Masaaki Ichinone, Akira Sekiguchi,* Yitzhak Apeloig*

Angew. Chem. Int. Ed. 2015, 54, 12144.

Activation of Homolytic Si-Zn and Si-Hg Bond Cleavage, Mediated by a Pt(0) Complex, via Novel Pt-Zn and Pt-Hg Compounds

Yosi Kratish , Gregory Molev, Arseni Kostenko, Dennis Sheberla, Boris Tumanskii, Mark Botoshansky, Shigeru Shimada, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig*

Angew. Chem. Int. Ed. 2015, 54, 11817.

Formation of Three New Bonds and Two Stereocenters in Acyclic Systems by Zinc-​Mediated Asymmetric Alkynylation of Acylsilanes, Brook-​Rearrangement and Ene-​Allene Carbocyclization Reactions

Polina Smirnov, Einat Katan, Jomon Mathew, Arseni Kostenko, Miriam Karni, Anne Nijs, Carsten Bolm, Yitzhak Apeloig,* Ilan Marek*

J. Org. Chem. 2014, 79 (24), 12122.

The 1-Phenyl-1-Trimethylsilyl Ethyl Cation: An NMR Spectroscopic and Computational Study of the α-Silyl Effect in Benzyl Cations

Arseni Kostenko, Bernhard Müller, Frank-Peter Kaufmann, Yitzhak Apeloig,* Hans-Ullrich Siehl*

Eur. J. Org. Chem. 2012, 1730.