Technische Universität München
Lehrstuhl für Anorganische und Metallorganische Chemie (Prof. Fischer)
Lichtenbergstr. 4
85748 Garching b. München
Multifunctional MOFs, Clusters and Composites
We develop functional molecular materials for advancing applications in energy conversion, catalysis, gas storage and separation, chemical sensing, photonics and microelectronics.
To illustrate, metal-rich complexes, atomic precise clusters, nanoparticles and nanocomposites can substitute rare noble metals for catalytic transformation of small molecules.
In addition, the combinatorial building-block principle of metal-organic frameworks (MOFs) yields ample opportunities for the manipulation and design of the chemistry of coordination space in pores and channels accessible to guest molecules. Our aim is to integrate chemical and physical multifunctionality in photo- and electro-active, catalytic and stimuli-responsive MOFs (see research overview).
Advanced Functional Materials
Abstract: Metal–organic frameworks (MOFs) are emerging as promising materials for multiphoton absorption (MPA), a nonlinear optical phenomenon relevant for applications, such as bioimaging, phototherapy, and…
Science Bulletin
Abstract: The electrochemical conversion of CO2 to ethylene glycol (EG) represents a sustainable pathway, reducing dependence on fossil fuels while avoiding CO2 emissions. Effectively regulating ethylene…
Advanced Functional Materials
Abstract: Coordination bond breakage and rearrangement offer a previously unexplored route to enhance the dielectric properties of metal–organic frameworks (MOFs). Here, we introduce a controlled…
Chemical Science
Abstract: The stabilization of zero oxidation state group (IV) metal centers in readily accessible compounds on a preparative scale remains a significant challenge. Substituting hydrocarbon ligands in the…
Angewandte Chemie - International Edition
Abstract: Monovalent gallium halides are intrinsically unstable compounds at room temperature and can only be generated in the gas phase at temperatures of about 1000 °C. Although they are isoelectronic to…
Angewandte Chemie - International Edition
Abstract: The heterobimetallic M14 cluster [Co3Ga2]H(μ2-GaTMP)9 (1, TMP = 2,2,6,6-tetramethylpiperidinyl) was obtained by treating CoCl2 with GaTMP in the presence of Mg and H2 as reduction additives. 1…
Advanced Functional Materials
ACS Catalysis
Abstract: Ethylene methoxycarbonylation (EMC) reaction, a key carbonylation process for methyl propionate production, typically relies on acid promoters and phosphine ligands in conventional homogeneous…
Advanced Functional Materials
Abstract: Coordination polymers (CPs) represent an innovative class of materials with proven potential for multiphoton absorption applications. However, understanding the structure-property relationships that…
Small Science
Abstract: Unlike 2D frameworks where conductivity is largely confined to in-plane transport, the scu topology offers 3D conduction pathways that enhance bulk charge mobility. When integrated with redox-active…
| Titel | Termine | Dauer | Art | Vortragende/r (Mitwirkende/r) |
|---|---|---|---|---|
| Aktuelle Themen und Forschungsstrategien in der Metall-Organischen Chemie (CH5215) |
|
2 | SE | |
| Allgemeine und Anorganische Chemie, Vorlesung (CH4101/CH4090a) |
|
4 | VO | |
| Allgemeine und Anorganische Chemie, Übung (CH4090b) |
|
1 | UE | |
| CRC-Vortragsreihe: "Distinguished Lecturer" |
|
2 | SE |
R. Fischer [L]
|
| Koordinationschemie - Struktur-Funktionsbeziehungen (CH3003) |
|
3 | VI | |
| Vortragsreihe: GDCh Kolloquium |
|
2 | KO |
R. Fischer [L]
|