Coordination Networks
Advanced Functional Materials
Prof. Roland Fischer
Prof. Dr. Roland Fischer
Technische Universität München
Lehrstuhl für Anorganische und Metallorganische Chemie (Prof. Fischer)
Postadresse
Lichtenbergstr. 4
85748 Garching b. München
- Tel.: +49 89 289 13080
- Raum: 5406.04.621G
- Homepage
- E-Mail: roland.fischer@tum.de
Research
Multifunctional MOFs, Clusters and Composites
We develop functional molecular materials for advancing applications in energy conversion, catalysis, gas storage and separation, chemical sensing, photonics and microelectronics.
To illustrate, metal-rich complexes, atomic precise clusters, nanoparticles and nanocomposites can substitute rare noble metals for catalytic transformation of small molecules.
In addition, the combinatorial building-block principle of metal-organic frameworks (MOFs) yields ample opportunities for the manipulation and design of the chemistry of coordination space in pores and channels accessible to guest molecules. Our aim is to integrate chemical and physical multifunctionality in photo- and electro-active, catalytic and stimuli-responsive MOFs (see research overview).
298 Publikationen
Polarization Regulation of Alkali-Treated Metal–Organic Frameworks for Dual-Functional Dielectrics
Advanced Functional Materials
Abstract: Coordination bond breakage and rearrangement offer a previously unexplored route to enhance the dielectric properties of metal–organic frameworks (MOFs). Here, we introduce a controlled…
Molecular Mimics of Intermetallic Phases
Angewandte Chemie - International Edition
Abstract: The heterobimetallic M14 cluster [Co3Ga2]H(μ2-GaTMP)9 (1, TMP = 2,2,6,6-tetramethylpiperidinyl) was obtained by treating CoCl2 with GaTMP in the presence of Mg and H2 as reduction additives. 1…
Homoleptic seven-coordinate Ti(0) and Zr(0) through a new stabilization mode
Chemical Science
Abstract: The stabilization of zero oxidation state group (IV) metal centers in readily accessible compounds on a preparative scale remains a significant challenge. Substituting hydrocarbon ligands in the…
Coordination-tailored conductive metal-organic frameworks boost CO2 electroreduction to ethylene for cascade ethylene glycol production
Science Bulletin
Abstract: The electrochemical conversion of CO2 to ethylene glycol (EG) represents a sustainable pathway, reducing dependence on fossil fuels while avoiding CO2 emissions. Effectively regulating ethylene…
A Redox-Active Tetrathiafulvalene-Based 3D Covalent Organic Framework with scu Topology for Controllable Charge Transport
Small Science
Abstract: Unlike 2D frameworks where conductivity is largely confined to in-plane transport, the scu topology offers 3D conduction pathways that enhance bulk charge mobility. When integrated with redox-active…
Asymmetric Ru–Co Dual Sites in Metal–Organic Frameworks for Heterogeneous Ethylene Methoxycarbonylation
ACS Catalysis
Abstract: Ethylene methoxycarbonylation (EMC) reaction, a key carbonylation process for methyl propionate production, typically relies on acid promoters and phosphine ligands in conventional homogeneous…
Design and characterisation of ZIF-8/alginate composites as drug carrier systems
Journal of Materials Chemistry B
Abstract: Metal-organic frameworks (MOFs) are promising candidates for drug carrier systems due to their high porosity and tuneable structures, however, their clinical translation is restrained. Integrating…
Trace Adsorptive Removal of PFAS from Water by Optimizing the UiO-66 MOF Interface
Advanced Materials
Abstract: The confluence of pervasiveness, bioaccumulation, and toxicity in freshwater contaminants presents an environmental threat second to none. Exemplifying this trifecta, per- and polyfluoroalkyl…
CO2 and Temperature Induced Switching of a Flexible Metal–Organic Framework with Surface-Mounted Nanoparticles
Small
Abstract: Within the material family of metal–organic frameworks (MOFs) the subclass of flexible MOFs (flexMOFs) has attracted great attention, showing structural flexibility as a response to external stimuli…
