Research on Conversion of CO2 at Technical University Munich 2020. Image: Andreas Heddergott / TUM
Black arsenic-phosphorus: semiconducting material with a 2D structure similar to that of graphene produced in the research group of Prof. Tom Nilges. Image: Andreas Battenberg / TUM
Prof. Dominik Bucher uses defects in diamond (NV-centers) as quantum sensors for NMR spectroscopy on the nano- to microscale. Image: Andreas Heddergott / TUM
Research on multifunctional supramolecular materials for energy storage and conversion at Image: Astrid Eckert / TUM
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Our Research
Our research areas can be divided according to two key aspects: “Chemistry and Energy” and “Chemistry of Sustainability”. Through our research, we try to address the most challenging issues of society’s present and near future. The associated research institutes on our campus also play an active role in our endeavour.
Chemistry and Energy
To satisfy society’s enormous energy demand, new concepts must be developed to store and harness energy in chemical bonds. Our Department of Chemistry addresses a wide range of feedstocks, synthetic fuels and storage systems. Research spans the investigation of microscopic chemical processes, the production of novel materials, and technology development.
In the Green Carbon Project, TUM biotechnologist Prof. Dr. Thomas Brück, from the Werner Siemens Chair of Synthetic Biotechnology, together with partner companies, explores how raw materials for carbon fiber components can be sustainably produced from algae and yeasts. Image: Andreas Heddergott / TUM
En route to a fully renewable material cycle, diversified feedstocks beyond oil must be tapped. This requires the development of efficient chemical conversion processes for feedstocks like shale gas as a bridge technology. Beyond these fossil resources, biomass acts as an alternative for the production of energy carriers. The development of renewable biogenic intermediates links research in the field of energy and sustainability.
View into the cavities of the catalyst. Image: Andreas Heddergott / TUM
The conversion of abundant water and carbon dioxide offers the potential for large scale production of synthetic fuels. Targets include hydrogenand hydrocarbons like methanol. Novel solutions for gas separation and storage are integral to the associated technologies.
Research on multifunctional supramolecular materials for energy storage and conversion at TUM. Image: Astrid Eckert / TUM
Sustainably generated electricity necessitates the development of efficient chemical systems for the storage and release of energy on demand. Routes comprise electrolyzers and fuel cells, batteries and thermoelectric materials.
Our planet Earth is energetically an open system but strictly closed in the availability of matter. Within these constraints, the chemistry of the future must respond to the needs of society. Thus, we need to meet the requirements imposed by limited resources while avoiding the emission of pollution to keep a balanced environment.
In the Green Carbon Project, TUM biotechnologist Prof. Dr. Thomas Brück, from the Werner Siemens Chair of Synthetic Biotechnology, together with partner companies, explores how raw materials for carbon fiber components can be sustainably produced from algae and yeasts. Image: Andreas Heddergott / TUM
Many current industrial processes are open chemical cycles as exemplified by CO2 emissions or inadequate resource disposal. Although chemistry can provide key solutions to close chemical cycles, this potential is far from being realized today. Research in the fields of carbon,nutrient and chemicals in water cycles is pursued to challenge this issue.
Sample holder with three single crystals, on whose surface the catalyst particles are deposited. Image: Andreas Heddergott / TUM
Contemporary chemical processes suffer from a lack of selectivity, generate undesired by-products and consume an excessive amount of energy. Catalysis is a key technology that addresses these challenges of process efficiency and also opens unprecedented routes to novel molecular structures. Key targets regarding process efficiency are: Low TemperatureTransformations, Selective Bond Activation and Dynamic Self-Organization.
Efficient conversion of natural gas: Embedded copper gives the zeolite its blue color. Image: Andreas Battenberg / TUM
Despite limited availability, current society relies on excessive use of resources. This implies that existing processes need to be revised in terms of resource efficiency. Excess waste streams and limited availability of crucial resources force us to rethink the economy of chemical reactions to get to a zero waste chemistry. This includes the examinationof earth abundant materials and the use of light harvesting systems.
Zeitschrift fur Anorganische und Allgemeine Chemie
Abstract: Along the research journey towards novel low-valent aluminum compounds, bulky σ-donor ligand adducts of aluminum(III) halides are prevalent synthons. These ligands’ steric and electronic properties…
Abstract: Anionic reagents with silicon-containing double bonds, M(R)Si═ERn (E = main group elements), have garnered significant interest owing to their unique metal-mediated reactivity and their potential in…
Abstract: Load cycling compromises the durability of proton exchange membrane fuel cells (PEMFCs), leading to a loss of the electrochemically active surface area (ECSA) of platinum in the cathode electrode.…
Harzer, Carla S.; Della Bella, Roberta K.F.; Gasteiger, Hubert A.
Abstract: Optically addressable spin systems have been widely studied for quantum-sensing applications. In this work, we demonstrate that photogenerated spin-correlated radical pairs in certain flavoproteins,…
Abstract: Here, we report a general workflow for the facile microwave-assisted synthesis of kinetically inert platinum(II)-metallacages (MCgs) and their post-assembly modification (PAM) via amide coupling and…
Willnhammer, Nina; Böhm, Felix A.; Vlaswinkel, Carlijn et al.
Abstract: The design of artificial photoenzymes by incorporating synthetic chromophores into proteins represents a promising strategy to achieve non-natural biocatalytic transformations with high levels of…
Boesen, Benedikt; Heider, Anna; O’Shea, Jack M. et al.
Abstract: Semi-empirical quantum-chemical methods such as extended tight-binding (xTB) models are widely used for large-scale simulations. Despite their popularity, their accuracy for transition-metal…
Moradi, Siyavash; Tomann, Rebecca; Head-Gordon, Martin; Stein, Christopher J.
Abstract: Li-substitution has been studied as an effective strategy to improve the structural stability and activate the O-redox in P2-type layered oxides as cathode materials for sodium-ion batteries. The…
Abstract: An unprecedented neutral “masked” non-external-donor-stabilized diborene is generated via intramolecular arene dearomatization of an N-heterocyclic imine (NHI)-supported free diborene. The free…
Zeitschrift fur Anorganische und Allgemeine Chemie
Abstract: Polyethylene oxide (PEO)-based solid polymer electrolytes (SPEs) have been extensively studied for all solid-state batteries (ASSBs) but still suffer from low thermal stability and ionic conductivity.…
Spranger, Robert J.; van Wüllen, Leo; Kirchberger, Anna; Nilges, Tom